HERSHEY'S natural unsweetened cocoa made of 100-percent cacao is a staple in every pantry. - Hershey's Cocoa 100% CACAO Natural Unsweetened Powder. - 100% CACAO Natural Unsweetened. From heavenly hot chocolate to fabulous frostings and gluten free desserts, this can of 100 percent cacao is naturally unsweetened, highly versatile and delicious.